»Next Generation«-batteries: Why we cannot speak of a post-lithium-ion era

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Modern societies rely heavily on batteries, as they enable a flexible and reliable energy supply by storing energy and releasing it again when needed. The basic principle is the same for all battery types, but the materials used can vary and determine the performance, energy density, service life, and environmental compatibility of the respective battery technology. 

What is coming after lithium-ion-batteries?

For decades, lithium-ion batteries (LIBs) have dominated the market for electrochemical energy storage and serve as the technological benchmark for numerous applications. Their high energy density, efficiency, and industrial maturity currently make them the most powerful and cost-effective solution.

At the same time, however, their technological, economic, and environmental limitations are becoming increasingly apparent. In particular, raw material dependencies and safety concerns are driving European industry, research, and policymakers to develop complementary battery technologies. As a result, the landscape of metal-ion batteries is becoming increasingly diverse. New material systems and cell concepts are being specifically researched and further developed to better address specific requirements.

These so-called “next-generation” batteries can be designed for specific applications and can thus efficiently serve specific market segments. Depending on the application area, the necessary capabilities regarding energy density or safety are enhanced, while less relevant ones are largely neglected.

safe & stable

Solid-state-batteries

A key feature of solid-state batteries is the solid state of the electrolytes, which are liquid in conventional LIBs. The solid-state electrolyte acts as the ion conductor.

 

Advantages

  • higher energy density
  • improved operational safety
  • increased stability

Disadvantages

  • low interfacial stability and resulting contact losses
  • mechanical pressure buildup required to ensure sufficient conductivity
  • complex and costly manufacturing
  • some new, unknown production processes

 

lightweight & recyclable

Lithium-sulfur-batteries

These batteries combine lithium as the anode material and sulfur as the cathode material, resulting in a high gravimetric energy density. 

 

Advantages

  • Higher energy density
  • Lower weight
  • Good recyclability 

Disadvantages

  • Limited cycle life and safety concerns
  • Complex production due to a specialized high-temperature process
  • Forming polysulfides can lead to gradual capacity loss

abundant & potential for autonomy

Sodium-ion-batteries (SIBs)

This battery composition is based on sodium ions as charge carriers. In terms of how they work and their structure, they are very similar to LIBs. 

Advantages

  • Widespread availability and cost-effectiveness 
  • Opportunity to potentially reduce geopolitical dependencies and establish more sustainable supply chains
  • Better performance at low temperatures

Disadvantages

  • Lower energy density than LIBs and lower storage capacity
  • No comprehensive, established infrastructure or supply chains yet

Insights from the field

Solid-state batteries

Solid-state batteries are currently transitioning from the laboratory and pilot phases to their first industrial applications. However, it is important to distinguish between different technological concepts: polymer-based, hybrid, or semi-solid-state systems are already more advanced and are being tested or are already in use in specific applications, whereas fully inorganic solid-state batteries are not yet mature enough for widespread industrial use. Key challenges remain, including unstable interfaces between electrodes and solid electrolytes, the need for external pressure in some cases, and new and significant requirements for scaled-up production processes.

Lithium-sulfur batteries

Lithium-sulfur batteries are still largely in the prototype and demonstration stages. Their great potential lies in their high theoretical gravimetric energy density and the use of low-cost, widely available materials. However, several technological hurdles continue to stand in the way of broader practical application. Of particular relevance are the polysulfide shuttle effect, which leads to active material loss and capacity degradation, limited cycle stability, and difficulties in practical cell design.

Sodium-ion batteries (SIBs)

Sodium-ion batteries have already reached a high level of technological maturity and are currently in the industrial ramp-up phase. They are considered particularly promising in applications where low cost, good availability of raw materials, safety, and robust performance at low temperatures are more important than maximum energy density. Due to their lower energy density compared to lithium-ion batteries, they are currently particularly suitable for stationary storage and micromobility applications (e.g., e-scooters, e-bikes). Their importance is expected to continue to grow in the coming years, particularly as a complement to established lithium-ion chemistries.

Philipp Voß

Research Associate, Materials

Fraunhofer Research Institution for Battery Cell Production FFB
Bergiusstraße 8
48165 Münster

Phone+49 251 48880238

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Fraunhofer FFB also views sodium-ion battery cell technology as a relevant field of research. Together with various partners, FFB is conducting research on SIBs, with the aim, among other things, of laying the groundwork for the further industrialization of the technology. To give you an idea of this area of research at Fraunhofer FFB, here are some of our projects. Would you like to learn more? Please feel free to contact our experts. You can find their contact information on the respective project pages.

In the two SIB:DE projects focused on research and development, Fraunhofer FFB and various partners aim to develop a sustainable, safe, and cost-effective alternative to lithium-ion batteries, evaluate the suitability of sodium-ion technology for the European energy and mobility transition, and drive industrial scaling.

In doing so, the participants can draw on existing infrastructure and process engineering expertise from LIB production for the manufacture of active materials, as well as for processing through to the cell and module Level. 

In collaboration with Fraunhofer ICT, Fraunhofer IPT, Voltfang, HI MS; IMD-4 and Manugy, Fraunhofer FFB is conducting research into the development and production of safe, long-lasting, and scalable SIBs for stationary applications. SIBs with a new electrolyte are being developed to enable the production of particularly safe and long-lasting sodium-ion batteries.

Research synergies and innovation dynamics of lithium-ion and sodium-ion batteries

Due to their advantages and relatively advanced technological maturity, SIBs are considered a reliable complement to LIBs, though they will not replace them in the long term.

A recently published study by a research team from Fraunhofer FFB, the University of Münster, ETH Zurich, and Stanford University found that battery technologies build upon one another to a large extent. There are significant knowledge flows within and between LIB and SIB battery technologies. These technological interdependencies are based on shared knowledge pathways regarding material concepts, cell architectures, and production processes. These knowledge transfers can be observed at both the product and process levels, underscoring the interdependence of manufacturing and design knowledge across chemical battery technologies. According to the researchers, knowledge already accumulated from LIB technologies thus significantly influences the development of new battery technologies such as SIBs.

A technological restart in the field of SIBs without prior knowledge of the design, functionality, and manufacturing of LIBs is thus proving to be significantly more difficult than previously assumed. Established market players have structural advantages over new entrants in the research and production of next-generation batteries due to their experiential knowledge, cross-chemical production and design expertise, and potentially existing infrastructure. This can lead to higher barriers to market entry, as new entrants cannot draw on knowledge accumulated over decades, nor on existing infrastructure and value chains.

It can therefore be concluded that companies and even countries that have not yet been among the leading players in the battery market cannot easily circumvent existing technological path dependencies by focusing directly on »Next Generation«-batteries.

Policy makers, industry, and research should therefore view metal-ion batteries as interdependent technologies rather than as isolated knowledge systems. The focus should be on supporting integrated research and development methods as well as platform capabilities that leverage manufacturing compatibility and existing design expertise across various battery cell types.

Rather than a post-lithium-ion era, what is emerging is a phase of technological coexistence and mutual development.

 

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Antonia Kasia Krüger

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Fraunhofer Research Institution for Battery Cell Production FFB
Bergiusstraße 8
48165  Münster

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Lena Ueberfeldt

Marketing Specialist

Fraunhofer Research Institution for Battery Cell Production FFB
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48165 Münster, Germany

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